Pumpellyite-(Mn++) Mineral Data
General Pumpellyite-(Mn++) Information
Chemical Formula:
Ca2(Mn++,Mg)(Al,Mn+++,Fe)2(SiO4)(Si2O7(OH)2•(H2O)
Composition:
Molecular Weight = 504.86 gm
Calcium 15.88 % Ca 22.22 % CaO
Magnesium 1.20 % Mg 2.00 % MgO
Manganese 16.32 % Mn 10.54 % MnO / 11.73 % Mn2 O3
Aluminum 5.34 % Al 10.10 % Al2 O3
Iron 2.77 % Fe 3.95 % Fe2 O3
Silicon 16.69 % Si 35.70 % SiO2
Hydrogen 0.60 % H 5.35 % H2 O
Oxygen 41.20 % O
______ ______
100.00 % 101.58 % = TOTAL OXIDE
Empirical Formula:
Ca2 Mn2+ 0.75 Mg0.25 AlMn3+ 0.75 Fe3+ 0.25 (SiO4 )(Si2 O7 )(OH)�(H2 O)
Environment:
Metamorphosed Mn-oxides in pelitic and dolomitic rocks.
IMA Status:
Approved IMA 1981
Locality:
Ochiai mine, Barazawa, Kohsai-cho, Yamanashi Prefecture, Japan. Link to MinDat.org Location Data.
Name Origin:
Named after the American geologist, R. Pumpelly (1837-1923).
Name Pronunciation:
Pumpellyite-(Mn++) + Pronunciation
Pumpellyite-(Mn++) Image
Images:
Pumpellyite-(Mn++)
Comments: BSE image of pumpellyite-(Mn++) (P) intercleaved with phlogopite (black) between braunite (white) and calcite (C).
Location: Mn oxide ores from the Precambrian Sausar Group, India. (AmMin, v76:241).
Scale: Scale Bar 0.01 cm.
© American Mineralogist
Pumpellyite-(Mn++) Crystallography
Axial Ratios:
a:b:c =1.4884:1:3.1953
Cell Dimensions:
a = 8.923, b = 5.995, c = 19.156, Z = 4; beta = 97.8° V = 1,015.24 Den(Calc)= 3.30
Crystal System:
Monoclinic - Prismatic H-M Symbol (2/m) Space Group: A2/m
X Ray Diffraction:
By Intensity(I/Io ): 2.93(1), 2.725(0.9), 4.75(0.65), 2.65(0.55), 2.53(0.5), 2.2(0.45), 4.43(0.35),
Physical Properties of Pumpellyite-(Mn++)
Cleavage:
{001} Good, {100} Good
Color:
Blue green, Olive green, Brown.
Density:
3.2
Diaphaneity:
Transparent to Translucent
Fracture:
Sub Conchoidal - Fractures developed in brittle materials characterized by semi-curving surfaces.
Habit:
Fibrous - Crystals made up of fibers.
Habit:
Massive - Lamellar - Distinctly foliated fine-grained forms.
Habit:
Spherical - Spherical, rounded aggregates.
Hardness:
5.5 - Knife Blade
Luster:
Vitreous (Glassy)
Streak:
white
Optical Properties of Pumpellyite-(Mn++)
Gladstone-Dale:
CI meas = -0.051 (Good) - where the CI = (1-KPDmeas /KC ) CI calc = -0.02 (Excellent) - where the CI = (1-KPDcalc /KC )
KPDcalc = 0.2371,KPDmeas = 0.2445,KC = 0.2325 Ncalc = 1.74 - 1.77
Optical Data:
Biaxial (+), a=1.752, b=1.795, g=1.8, bire=0.0480, 2V(Calc)=36, 2V(Meas)=40-50.
Calculated Properties of Pumpellyite-(Mn++)
Electron Density:
Bulk Density (Electron Density)=3.26 gm/cc note: Specific Gravity of Pumpellyite-(Mn++) =3.30 gm/cc.
Fermion Index:
Fermion Index = 0.0099967154 Boson Index = 0.9900032846
Photoelectric:
PEPumpellyite-(Mn++) = 7.71 barns/electronU=PEPumpellyite-(Mn++) x r Electron Density= 25.11 barns/cc.
Radioactivity:
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Pumpellyite-(Mn++) is Not Radioactive
Pumpellyite-(Mn++) Classification
Dana Class:
58.02.02.08 (58) Sorosilicate Insular, Mixed, Single, and Larger Tetrahedral Groups
(58.02) with cations in [6] and higher coordination; single and double groups (n=1,2)
(58.02.02) Pumpellyite group
58.02.02.01 Julgoldite-(Fe++) Ca2Fe(Fe,Al)2(SiO4)(Si2O7)(OH)2•(H2O) C 2/m 2/m
58.02.02.02 Julgoldite-(Fe+++) Ca2Fe(Fe,Al)2(SiO4)(Si2O7)(O,OH)2•(H2O) A2/m 2/m
58.02.02.03 Okhotskite-(Mg) * Ca3(Mg,Mn)(Mn,Al,Fe)(SiO4)(Si2O7)(OH)2•(H2O) Mono
58.02.02.04 Okhotskite-(Mn++) Ca2(Mn,Mg)(Mn,Al,Fe)Si3O10(OH)4 A2/m 2/m
58.02.02.05 Pumpellyite-(Fe++) Ca2Fe(Al,Fe)2(SiO4)(Si2O7)(OH)2•(H2O) A2/m 2/m
58.02.02.06 Pumpellyite-(Fe+++) Ca2FeAl2(SiO4)(Si2O7)(OH,O)2•(H2O) A2/m 2/m
58.02.02.07 Pumpellyite-(Mg) Ca2MgAl2(SiO4)(Si2O7)(OH)2•(H2O) A2/m 2/m
58.02.02.08 Pumpellyite-(Mn++) Ca2(Mn,Mg)(Al,Mn,Fe)2(SiO4)(Si2O7(OH)2•(H2O) A2/m 2/m
58.02.02.09 Shuiskite Ca2(Mg,Al)(Cr,Al)2(SiO4)(Si2O7)(OH)2•(H2O) A2/m 2/m
58.02.02.10 Poppiite ! Ca2(V,Fe,Mg)(V,Al)2(Si,Al)3(O,OH)14 C 2/m 2/m
58.02.02.11 Pumpellyite-(Al) ! Ca2(Al,Fe,Mg)Al2(SiO4)(Si2O7)(OH,O)2•H2O A2/m 2/m
Strunz Class:
09.BG.20 09 - SILICATES (Germanates)
09.B - Sorosilicates
09.BG -Sorosilicates with mixed SiO4 and Si2O7 groups;
09.BG.20 Julgoldite-(Fe++) Ca2Fe(Fe,Al)2(SiO4)(Si2O7)(OH)2•(H2O) C 2/m 2/m
09.BG.20 Julgoldite-(Fe+++) Ca2Fe(Fe,Al)2(SiO4)(Si2O7)(O,OH)2•(H2O) A2/m 2/m
09.BG.20 Pumpellyite-(Fe++) Ca2Fe(Al,Fe)2(SiO4)(Si2O7)(OH)2•(H2O) A2/m 2/m
09.BG.20 Okhotskite-(Mg) * Ca3(Mg,Mn)(Mn,Al,Fe)(SiO4)(Si2O7)(OH)2•(H2O) Mono
09.BG.20 Okhotskite-(Mn++) Ca2(Mn,Mg)(Mn,Al,Fe)Si3O10(OH)4 A2/m 2/m
09.BG.20 Pumpellyite-(Fe+++) Ca2FeAl2(SiO4)(Si2O7)(OH,O)2•(H2O) A2/m 2/m
09.BG.20 Pumpellyite-(Mg) Ca2MgAl2(SiO4)(Si2O7)(OH)2•(H2O) A2/m 2/m
09.BG.20 Pumpellyite-(Mn++) Ca2(Mn,Mg)(Al,Mn,Fe)2(SiO4)(Si2O7(OH)2•(H2O) A2/m 2/m
09.BG.20 Shuiskite Ca2(Mg,Al)(Cr,Al)2(SiO4)(Si2O7)(OH)2•(H2O) A2/m 2/m
09.BG.20 Pumpellyite-(Al) ! Ca2(Al,Fe,Mg)Al2(SiO4)(Si2O7)(OH,O)2•H2O A2/m 2/m
09.BG.20 Poppiite ! Ca2(V,Fe,Mg)(V,Al)2(Si,Al)3(O,OH)14 C 2/m 2/m
Other Pumpellyite-(Mn++) Information
References:
NAME( Duda&Rejl90) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(Dana8)
See Also:
Links to other databases for Pumpellyite-(Mn++) :
1 - Am. Min. Crystal Structure Database
2 - Athena
3 - GeoScienceWorld
4 - Google Images
5 - Google Scholar
6 - MinDAT
7 - Mineralienatlas (Deutsch)
8 - Online Mineral Museum
9 - QUT Mineral Atlas
10 - Ruff.Info
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Pumpellyite-(Mn++)
Ca2(Mn++,Mg)(Al,Mn+++,Fe)2(SiO4)(Si2O7(OH)2•(H2O)
Dana No: 58.02.02.08 Strunz No: 09.BG.20
Locality:
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