Woodwardite Mineral Data
General Woodwardite Information
Chemical Formula:
Cu4Al2(SO4)(OH)12•2-4(H2O)
Composition:
Molecular Weight = 662.34 gm
Aluminum 8.15 % Al 15.39 % Al2 O3
Copper 38.38 % Cu 48.04 % CuO
Hydrogen 2.74 % H 24.48 % H2 O
Sulfur 4.84 % S 12.09 % SO3
Oxygen 45.90 % O
______ ______
100.00 % 100.00 % = TOTAL OXIDE
Empirical Formula:
Cu4 Al2 (SO4 )(OH)12 •3(H2 O)
Environment:
Inadequately characterized mineral. Post mining alteration product.
IMA Status:
Valid Species (Pre-IMA) 1866
Locality:
Cornwall, England. Link to MinDat.org Location Data.
Name Origin:
Named for Samuel P. Woodward (1821-1865), English naturalist and geologist.
Name Pronunciation:
Woodwardite + Pronunciation
Woodwardite Image
Images:
Woodwardite Crystallography
Axial Ratios:
a:c = 1:4.54999
Cell Dimensions:
a = 6, c = 27.3, Z = 2; V = 851.13 Den(Calc)= 2.58
Crystal System:
Hexagonal Space Group: Unk
X Ray Diffraction:
By Intensity(I/Io ): 10.9(1), 5.46(0.6), 3.66(0.5),
Physical Properties of Woodwardite
Color:
Greenish blue, Turquoise.
Density:
2.38
Diaphaneity:
Translucent
Habit:
Botryoidal - "Grape-like" rounded forms (e.g.. malachite).
Habit:
Fibrous - Crystals made up of fibers.
Streak:
light blue
Optical Properties of Woodwardite
Gladstone-Dale:
CI meas = -0.089 (Poor) - where the CI = (1-KPDmeas /KC ) CI calc = -0.005 (Superior) - where the CI = (1-KPDcalc /KC )
KPDcalc = 0.2192,KPDmeas = 0.2376,KC = 0.2182 Ncalc = 1.52 - 1.56
Optical Data:
Biaxial (+), a=1.552-1.571, b=1.555-1.574, g=1.565-1.576, bire=0.0050-0.0130
Calculated Properties of Woodwardite
Electron Density:
Bulk Density (Electron Density)=2.56 gm/cc note: Specific Gravity of Woodwardite =2.58 gm/cc.
Fermion Index:
Fermion Index = 0.0005875053 Boson Index = 0.9994124947
Photoelectric:
PEWoodwardite = 16.93 barns/electronU=PEWoodwardite x r Electron Density= 43.27 barns/cc.
Radioactivity:
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Woodwardite is Not Radioactive
Woodwardite Classification
Dana Class:
31.02.02.01 (31) Hydrated Sulfates Containing Hydroxyl or Halogen
(31.02) where (A+ B++)6 (XO4) Zq�x(H2O)
(31.02.02) Woodwardite Group
31.02.02.01 Woodwardite Cu4Al2(SO4)(OH)12•2-4(H2O) Unk Hex
31.02.02.02 Hydrowoodwardite ! Cu1-xAlx(OH)2(SO4)x/2•n(H2O)with0<x<0.67andn>3x/2 R 3 m 3 2/m
31.02.02.03 Zincowoodwardite ! [Zn1-xAlx(OH)2][(SO4)x/2(H2O)n] P 3- or R 3 m 3
31.02.02.03a Zincowoodwardite-1T ! [Zn1BxAlx(OH)2][(SO4)x/2•n(H2O)],x=0.33,n.0.96 P 3 3
31.02.02.03b Zincowoodwardite-3R ! [Zn1BxAlx(OH)2][(SO4)x/2•n(H2O)],0.32<x<0.50,n=0.59 R 3 m 3 2/m
Strunz Class:
07.DD.35 07 - SULFATES (SELENATES, TELLURATES)
07.D - Sulfates (selenates, etc.) with additional anions, with H2O
07.DD -With only medium-sized cations; sheets of edge-sharing octahedra
07.DD.35 Carrboydite (Ni,Cu)14Al9(SO4,CO3)6(OH)43•7(H2O) Unk Hex
07.DD.35 Glaucocerinite (Zn,Cu)5Al3(SO4)1.5(OH)16•9(H2O) Unk (HEX-R) Trig
07.DD.35 Honessite Ni6Fe2(SO4)(OH)16•4(H2O) R 3 m 3 2/m
07.DD.35 Hydrowoodwardite ! Cu1-xAlx(OH)2(SO4)x/2•n(H2O)with0<x<0.67andn>3x/2 R 3 m 3 2/m
07.DD.35 Zincowoodwardite ! [Zn1-xAlx(OH)2][(SO4)x/2(H2O)n] P 3- or R 3 m 3
07.DD.35 Hydrohonessite Ni6Fe2(SO4)(OH)16•7(H2O) Unk Hex
07.DD.35 Motukoreaite Na2Mg38Al24(CO3)13(SO4)8(OH)108•56(H2O) R 3 m 3 2/m
07.DD.35 Mountkeithite (Mg,Ni)11(Fe,Cr)3(SO4,CO3)3.5(OH)24•11(H2O) Unk Hex
07.DD.35 Shigaite Mn7Al4(SO4)2(OH)22•8(H2O) R 3 3
07.DD.35 Natroglaucocerinite ! (Na,Zn,Cu)10Al6(SO4)3(OH)32•18(H2O)? Unk
07.DD.35 Wermlandite (Ca,Mg)Mg7(Al,Fe)2(SO4)2(OH)18•12(H2O) P 3 c1 3 2/m
07.DD.35 Nikischerite ! NaFe6Al3(SO4)2(OH)18(H2O)12 R 3 3
07.DD.35 Zincaluminite Zn6Al6(SO4)2(OH)26•5(H2O) Unk Hex
07.DD.35 Woodwardite Cu4Al2(SO4)(OH)12•2-4(H2O) Unk Hex
07.DD.35 Zincowoodwardite-3R ! [Zn1BxAlx(OH)2][(SO4)x/2•n(H2O)],0.32<x<0.50,n=0.59 R 3 m 3 2/m
07.DD.35 Zincowoodwardite-1T ! [Zn1BxAlx(OH)2][(SO4)x/2•n(H2O)],x=0.33,n.0.96 P 3 3
Other Woodwardite Information
References:
NAME( Dana8) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(Enc. of Minerals,2nd ed.,1990)
See Also:
Links to other databases for Woodwardite :
1 - Am. Min. Crystal Structure Database
2 - Athena
3 - EUROmin Project
4 - Ecole des Mines de Paris
5 - GeoScienceWorld
6 - Google Images
7 - Google Scholar
8 - Handbook of Mineralogy (MinSocAm)
9 - Handbook of Mineralogy (UofA)
10 - MinDAT
11 - Mineralienatlas (Deutsch)
12 - Online Mineral Museum
13 - QUT Mineral Atlas
14 - Ruff.Info
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Woodwardite
Cu4Al2(SO4)(OH)12•2-4(H2O)
Dana No: 31.02.02.01 Strunz No: 07.DD.35
Locality:
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