Zaccagnaite Mineral Data
General Zaccagnaite Information
Chemical Formula:
Zn4Al2(OH)12(CO3)•3(H2O)
Composition:
Molecular Weight = 629.83 gm
Aluminum 9.00 % Al 17.00 % Al2 O3
Zinc 40.49 % Zn 50.40 % ZnO
Hydrogen 2.88 % H 25.74 % H2 O
Carbon 1.91 % C 6.99 % CO2
Oxygen 45.73 % O
______ ______
100.00 % 100.13 % = TOTAL OXIDE
Empirical Formula:
Zn3.9 Al2.1 (OH)12 (CO3 )•3(H2 O)
Environment:
Hydrothermal alteration product of sphalerite and Al-rich fluids in calcite vein cavities within the Carrara marble. A member of the hydrotalcite-manasseite groups.
IMA Status:
Approved IMA 1997 (Dana # Added)
Locality:
Gioia quarry, Colonnata valley, Carrara basin region, Apuan Alps, Italy. Link to MinDat.org Location Data.
Name Origin:
Named for Domenico Zaccagna (1851-1940) who published the first geologic map of the Apuan Alps and a collector of minerals from the Carrara Marble.
Synonym:
IMA1997-019
Zaccagnaite Image
Images:
Images:
Zaccagnaite Fraipontite
Comments: Scanning electron microscope image of hexagonal, tapering, prismatic zaccagnaite crystals, covered by a thin crust of fraipontite. (AmMin 86:1294).
Location: Marble quarries of the Carrara basin (Apuan Alps, Italy).
Scale: See Image.
© American Mineralogist
Zaccagnaite Crystallography
Axial Ratios:
a:c = 1:4.91895
Cell Dimensions:
a = 3.0725, c = 15.1135, Z = 0.3333; V = 123.56 Den(Calc)= 2.82
Crystal System:
Hexagonal - Dihexagonal Dipyramidal H-M Symbol (6/m 2/m 2/m) Space Group: P 63 /mmc
X Ray Diffraction:
By Intensity(I/Io ): 7.51(1)(002), 1.542(0.75)(108), 1.539(0.75)(110), 3.794(0.5)(004), 1.83(0.4)(106), 2.175(0.4)(104), 2.511(0.4)(102), 1.89(0.25)(008), 2.65(0.25)(100),
Physical Properties of Zaccagnaite
Color:
White, Colorless.
Diaphaneity:
Transparent
Habit:
Hexagonal - Six-sided crystal shape in cross-section or habit.
Habit:
Microscopic Crystals - Crystals visible only with microscopes.
Habit:
Prismatic - Crystals Shaped like Slender Prisms (e.g. tourmaline).
Luster:
Vitreous (Glassy)
Streak:
white
Optical Properties of Zaccagnaite
Optical Data:
Uniaxial (?).
NCalc= 1.61 - from Gladstone-Dale relationship (KC = 0.2171) where Ncalc =Dcalc *KC +1
Calculated Properties of Zaccagnaite
Electron Density:
Bulk Density (Electron Density)=2.80 gm/cc note: Specific Gravity of Zaccagnaite =2.82 gm/cc.
Fermion Index:
Fermion Index = 0.01 Boson Index = 0.99
Photoelectric:
PEZaccagnaite = 19.89 barns/electronU=PEZaccagnaite x r Electron Density= 55.64 barns/cc.
Radioactivity:
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Zaccagnaite is Not Radioactive
Zaccagnaite Classification
Dana Class:
16b.06.01.04 (16b) Carbonates - Hydroxyl or Halogen
(16b.06) Dana Type
(16b.06.01) Sjorgrenite-Hydrotalcite Group (Sojogrenite Subgroup:Hexagonal)
16b.06.01.01 Manasseite Mg6Al2(CO3)(OH)16•4(H2O) P 63 /mmc 6/m 2/m 2/m
16b.06.01.02 Barbertonite Mg6Cr2(CO3)(OH)16•4(H2O) P 63 /mmc 6/m 2/m 2/m
16b.06.01.03 Sjogrenite Mg6Fe2(CO3)(OH)16•4(H2O) P 63 /mmc 6/m 2/m 2/m
16b.06.01.04 Zaccagnaite ! Zn4Al2(OH)12(CO3)•3(H2O) P 63 /mmc 6/m 2/m 2/m
Strunz Class:
05.DA.45 05 - CARBONATES (NITRATES)
05.D - Carbonates with Additional Anions, with H2O
05.DA -With medium-sized cations
05.DA.45 Brugnatellite Mg6Fe(CO3)(OH)13•4(H2O) P 63 /mmc 6/m 2/m 2/m
05.DA.45 Barbertonite Mg6Cr2(CO3)(OH)16•4(H2O) P 63 /mmc 6/m 2/m 2/m
05.DA.45 Chlormagaluminite (Mg,Fe)4Al2(OH)12(Cl2,CO3)•2(H2O) P 6/mcm, P 6cm, P 6 c2 Hex
05.DA.45 Zaccagnaite ! Zn4Al2(OH)12(CO3)•3(H2O) P 63 /mmc 6/m 2/m 2/m
05.DA.45 Manasseite Mg6Al2(CO3)(OH)16•4(H2O) P 63 /mmc 6/m 2/m 2/m
05.DA.45 Sjogrenite Mg6Fe2(CO3)(OH)16•4(H2O) P 63 /mmc 6/m 2/m 2/m
Other Zaccagnaite Information
References:
NAME( AmMin, Vol 86, p 1293-1301) PHYS. PROP.(AmMin, Vol 86, p 1293-1301) OPTIC PROP.(AmMin, Vol 86, p 1293-1301)
See Also:
Links to other databases for Zaccagnaite :
1 - Am. Min. Crystal Structure Database
2 - Athena
3 - GeoScienceWorld
4 - Google Images
5 - Google Scholar
6 - Handbook of Mineralogy (MinSocAm)
7 - Handbook of Mineralogy (UofA)
8 - MinDAT
9 - Mineralienatlas (Deutsch)
10 - Online Mineral Museum
11 - QUT Mineral Atlas
12 - Ruff.Info
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Zaccagnaite
Zn4Al2(OH)12(CO3)•3(H2O)
Dana No: 16b.06.01.04 Strunz No: 05.DA.45
Locality:
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