Organovaite-Zn Mineral Data
General Organovaite-Zn Information
Chemical Formula:
K2Zn(Nb,Ti)4(Si4O12)2(O,OH)4•6(H2O)
Composition:
Molecular Weight = 2,439.14 gm
Potassium 3.05 % K 3.67 % K2 O
Barium 2.25 % Ba 2.51 % BaO
Sodium 0.47 % Na 0.64 % Na2 O
Calcium 0.82 % Ca 1.15 % CaO
Titanium 6.28 % Ti 10.48 % TiO2
Manganese 0.45 % Mn 0.58 % MnO
Niobium 18.28 % Nb 26.15 % Nb2 O5
Aluminum 0.22 % Al 0.42 % Al2 O3
Zinc 4.29 % Zn 5.34 % ZnO
Iron 0.23 % Fe 0.29 % FeO
Silicon 18.19 % Si 38.92 % SiO2
Hydrogen 1.12 % H 10.01 % H2 O
Oxygen 44.34 % O
______ ______
100.00 % 100.16 % = TOTAL OXIDE
Empirical Formula:
K1.9 Na0.5 Ca0.5 Ba0.4 Zn1.6 Mn2+ 0.2 Fe2+ 0.1 Nb4.8 Ti3.2 Si15.8 Al0.2 O52.5 (OH)3.1 �12(H2 O)
Environment:
Alkaline pegmatites. Sometimes forms pseudomorphs after vuonnemite. Labuntsovite group; structure.
IMA Status:
Approved IMA 2002 (Dana # Added)
Locality:
Karnasurt Mountain, Lovozero massif, Kola Peninsula, Russia. Link to MinDat.org Location Data.
Name Origin:
Named for Natalia Ivanovna Organova (1929-), Russian crystallographer and the Zn end-member.
Synonym:
IMA2001-006
Organovaite-Zn Image
Images:
Organovaite-Zn
Comments: Crude pinkish-brown organovaite-Zn crystals in matrix.
Location: Mt. Karnasurt, Lovozero, Kola Peninsula, Russia.
Scale: Specimen Size 1x2.5 cm.
© Diederik Visser
Organovaite-Zn Crystallography
Axial Ratios:
a:b:c =1.0436:1:1.1247
Cell Dimensions:
a = 14.535, b = 13.927, c = 15.665, Z = 1; beta = 117.6° V = 2,810.20 Den(Calc)= 1.44
Crystal System:
Monoclinic - Prismatic H-M Symbol (2/m) Space Group: C 2/m
X Ray Diffraction:
By Intensity(I/Io ): 6.96(1)(020,002), 3.222(0.84)(422 ,400,404 3.114(0.66)(042,024),
2.514(0.3)(442 ,402), 4.924(0.3)(022), 6.43(0.24)(200,202 ), 1.43(0.22),
Physical Properties of Organovaite-Zn
Cleavage:
None
Color:
Pink, Pinkish brown, White.
Density:
2.88
Diaphaneity:
Translucent
Fracture:
Brittle - Uneven - Very brittle fracture producing uneven fragments.
Habit:
Prismatic - Crystals Shaped like Slender Prisms (e.g. tourmaline).
Habit:
Pseudomorphous - Occurs in the form of another mineral.
Hardness:
5 - Apatite
Luster:
Vitreous (Glassy)
Streak:
white
Optical Properties of Organovaite-Zn
Gladstone-Dale:
CI meas = 0.007 (Superior) - where the CI = (1-KPDmeas /KC ) CI calc = -0.986 (Poor) - where the CI = (1-KPDcalc /KC )
KPDcalc = 0.4991,KPDmeas = 0.2495,KC = 0.2513 Ncalc = 1.36 - 1.72
Optical Data:
Biaxial (+), a=1.683, b=1.688, g=1.785, bire=0.1020
Calculated Properties of Organovaite-Zn
Electron Density:
Bulk Density (Electron Density)=2.81 gm/cc note: Specific Gravity of Organovaite-Zn =2.88 gm/cc.
Fermion Index:
Fermion Index = 0.02 Boson Index = 0.98
Photoelectric:
PEOrganovaite-Zn = 40.28 barns/electronU=PEOrganovaite-Zn x r electron = 113.04 barns/cc.
Radioactivity:
GRapi = 42.83 (Gamma Ray American Petroleum Institute Units)
Concentration of Organovaite-Zn per GRapi unit = 2.33 (%)
Estimated Radioactivity from Organovaite-Zn - barely detectable
Organovaite-Zn Classification
Dana Class:
60.01.03h.02 (60) Cyclosilicate Four-Membered Rings
(60.01) as Titanosilicates
(60.01.03h) Labuntsovite Group (Organovaite subgroup Monoclinic [C2/m])
60.01.03h.01 Organovaite-Mn ! K2Mn(Nb,Ti)4(Si4O12)2(O,OH)4•6(H2O) Cm m
60.01.03h.02 Organovaite-Zn ! K2Zn(Nb,Ti)4(Si4O12)2(O,OH)4•6(H2O) C 2/m 2/m
60.01.03h.03 Parakuzmenkoite-Fe ! (K,Ba)2Fe(Ti,Nb)4(Si4O12)2(O,OH)4•7(H2O) C 2/m 2/m
Strunz Class:
09.CE.30g 09 - SILICATES (Germanates)
09.C - Cyclosilicates
09.CE -[Si4O12]8- 4-membered single rings (vierer-Einfachringe),
09.CE.30g Parakuzmenkoite-Fe ! (K,Ba)2Fe(Ti,Nb)4(Si4O12)2(O,OH)4•7(H2O) C 2/m 2/m
09.CE.30g Organovaite-Zn ! K2Zn(Nb,Ti)4(Si4O12)2(O,OH)4•6(H2O) C 2/m 2/m
09.CE.30g Organovaite-Mn ! K2Mn(Nb,Ti)4(Si4O12)2(O,OH)4•6(H2O) Cm m
Other Organovaite-Zn Information
References:
NAME( AmMin, v 88, p 932) PHYS. PROP.(AmMin, v 88, p 932) OPTIC PROP.(AmMin, v 88, p 932)
See Also:
Links to other databases for Organovaite-Zn :
1 - Am. Min. Crystal Structure Database
2 - Athena
3 - GeoScienceWorld
4 - Google Images
5 - Google Scholar
6 - MinDAT
7 - Mineralienatlas (Deutsch)
8 - Online Mineral Museum
9 - QUT Mineral Atlas
10 - Ruff.Info
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Organovaite-Zn
K2Zn(Nb,Ti)4(Si4O12)2(O,OH)4•6(H2O)
Dana No: 60.01.03h.02 Strunz No: 09.CE.30g
Locality:
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