Graeserite Mineral Data
General Graeserite Information
Chemical Formula:
(Fe+++,Ti)4Ti3AsO13(OH)
Composition:
Molecular Weight = 666.95 gm
Titanium 21.54 % Ti 35.93 % TiO2
Iron 33.49 % Fe 47.89 % Fe2 O3
Arsenic 11.23 % As 14.83 % As2 O3
Hydrogen 0.15 % H 1.35 % H2 O
Oxygen 33.58 % O
______ ______
100.00 % 100.00 % = TOTAL OXIDE
Empirical Formula:
Fe3+ 4 Ti3 AsO13 (OH)
Environment:
The Fe++ dominant analog of tomichite and the As+++ dominant analog of derbylite. In hydrothermal veins in a two-mica paragneiss.
IMA Status:
Approved IMA 1998 (Dana # Added)
Locality:
Larchelitini, in the Monte Leone Nappe, Binntal region, western Alps, Switzerland. Link to MinDat.org Location Data.
Name Origin:
For Prof. Dr. Stefan Graeser (1935-), in recognition of his extensive research on the oxides and sulfosalts of arsenic in the Binntal region of Switzerland.
Name Pronunciation:
Graeserite + Pronunciation
Synonym:
ICSD 50374
IMA1996-010
Graeserite Image
Images:
Graeserite
Comments: SEM photomicrograph of an aggregate of hair-like graeserite crystals. CanMin v36:1083.
Location: Monte Leone Nappe, Binntal region, Western Alps, Switzerland.
Scale: Scale Bar 1 mm.
© Canadian Mineralogist
Graeserite Crystallography
Axial Ratios:
a:b:c =0.5027:1:0.3503
Cell Dimensions:
a = 7.184, b = 14.289, c = 5.006, Z = 2; beta = 105.17° V = 495.97 Den(Calc)= 4.47
Crystal System:
Monoclinic - Prismatic H-M Symbol (2/m) Space Group: A2/m
X Ray Diffraction:
By Intensity(I/Io ): 2.681(1), 2.846(0.8), 1.5825(0.5),
Physical Properties of Graeserite
Cleavage:
{100} Distinct
Color:
Black.
Density:
4.62
Diaphaneity:
Opaque
Fracture:
Conchoidal - Fractures developed in brittle materials characterized by smoothly curving surfaces, (e.g. quartz).
Habit:
Acicular - Occurs as needle-like crystals.
Habit:
Aggregates - Made of numerous individual crystals or clusters.
Habit:
Radial - Crystals radiate from a center without producing stellar forms (e.g. stibnite)
Hardness:
5.5 - Knife Blade
Luster:
Metallic
Streak:
black
Optical Properties of Graeserite
Optical Data:
NCalc= 2.48 - from Gladstone-Dale relationship (KC = 0.3315) where Ncalc =Dcalc *KC +1 NCalc= 2.53 - from Gladstone-Dale relationship (KC = 0.3315) where Ncalc =Dmeas *KC +1
Calculated Properties of Graeserite
Electron Density:
Bulk Density (Electron Density)=4.24 gm/cc note: Specific Gravity of Graeserite =4.47 gm/cc.
Fermion Index:
Fermion Index = 0.03 Boson Index = 0.97
Photoelectric:
PEGraeserite = 21.57 barns/electronU=PEGraeserite x r Electron Density= 91.37 barns/cc.
Radioactivity:
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Graeserite is Not Radioactive
Graeserite Classification
Dana Class:
46.02.03.03 (46) Basic or Halogen-Containing Antimonites, Arsenites and Phosphites
(46.02) with miscellaneous formulae
(46.02.03) Derbylite Group
46.02.03.01 Tomichite (V,Fe)4Ti3AsO13(OH) A2/m 2/m
46.02.03.02 Derbylite (Fe,Fe,Ti)7SbO13(OH) P 21 /m 2/m
46.02.03.03 Graeserite ! (Fe,Ti)4Ti3AsO13(OH) A2/m 2/m
Strunz Class:
04.JB.55 04 - OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodate
04.J - Arsenites, Antimonites, Bismuthites, Sulfites,
04.JB -Arsenites, antimonites, bismuthites; with additional anions, without H2O
04.JB.55 Derbylite (Fe,Fe,Ti)7SbO13(OH) P 21 /m 2/m
04.JB.55 Graeserite ! (Fe,Ti)4Ti3AsO13(OH) A2/m 2/m
04.JB.55 Tomichite (V,Fe)4Ti3AsO13(OH) A2/m 2/m
Other Graeserite Information
References:
NAME( MinRec) PHYS. PROP.(MinRec)
See Also:
Links to other databases for Graeserite :
1 - Am. Min. Crystal Structure Database
2 - Athena
3 - GeoScienceWorld
4 - Google Images
5 - Google Scholar
6 - Handbook of Mineralogy (UofA)
7 - MinDAT
8 - Mineralienatlas (Deutsch)
9 - Online Mineral Museum
10 - QUT Mineral Atlas
11 - Ruff.Info
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Graeserite
(Fe+++,Ti)4Ti3AsO13(OH)
Dana No: 46.02.03.03 Strunz No: 04.JB.55
Locality:
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