Whitmoreite Mineral Data
General Whitmoreite Information
Chemical Formula:
Fe++Fe+++2(PO4)2(OH)2•4(H2O)
Composition:
Molecular Weight = 463.56 gm
Iron 36.14 % Fe 46.50 % FeO
Phosphorus 13.36 % P 30.62 % P2 O5
Hydrogen 2.17 % H 19.43 % H2 O
Oxygen 48.32 % O
______ ______
100.00 % 96.55 % = TOTAL OXIDE
Empirical Formula:
Fe2+ Fe2+ 2 (PO4 )2 (OH)2 •4(H2 O)
Environment:
Hydrothermal alteration product of triphylite in cavities in quartz-bearing pegmatite.
IMA Status:
Approved IMA 1974
Locality:
Palermo No. 1 mine, North Groton, New Hampshire, USA. Link to MinDat.org Location Data.
Name Origin:
Named for Robert W. Whitmore (1936-), Micromount mineral collector and owner of the Palermo mine, New Hampshire, USA.
Name Pronunciation:
Whitmoreite + Pronunciation
Synonym:
ICSD 6202
PDF 26-1138
Whitmoreite Image
Images:
Whitmoreite Crystallography
Axial Ratios:
a:b:c =1.0277:1:0.5622
Cell Dimensions:
a = 10, b = 9.73, c = 5.471, Z = 2; beta = 93.8° V = 531.16 Den(Calc)= 2.90
Crystal System:
Monoclinic - Prismatic H-M Symbol (2/m) Space Group: P 21 /c
X Ray Diffraction:
By Intensity(I/Io ): 10.05(1), 4.98(0.7), 7.01(0.7),
Physical Properties of Whitmoreite
Cleavage:
{100} Good
Color:
Brown, Greenish brown, Light yellow brown, Dark brown.
Density:
2.87
Diaphaneity:
Transparent to Translucent
Habit:
Acicular - Occurs as needle-like crystals.
Habit:
Aggregates - Made of numerous individual crystals or clusters.
Habit:
Radial - Crystals radiate from a center without producing stellar forms (e.g. stibnite)
Hardness:
3 - Calcite
Luster:
Vitreous - Adamantine
Optical Properties of Whitmoreite
Gladstone-Dale:
CI meas = -0.19 (Poor) - where the CI = (1-KPDmeas /KC ) CI calc = -0.177 (Poor) - where the CI = (1-KPDcalc /KC )
KPDcalc = 0.2467,KPDmeas = 0.2492,KC = 0.2095 Ncalc = 1.6 - 1.61
Optical Data:
Biaxial (-), a=1.676, b=1.725, g=1.745, bire=0.0690, 2V(Calc)=62, 2V(Meas)=60-65.
Pleochroism (x):
light green brown.
Pleochroism (y):
light green brown.
Pleochroism (z):
dark green brown.
Calculated Properties of Whitmoreite
Electron Density:
Bulk Density (Electron Density)=2.88 gm/cc note: Specific Gravity of Whitmoreite =2.90 gm/cc.
Fermion Index:
Fermion Index = 0.0078973614 Boson Index = 0.9921026386
Photoelectric:
PEWhitmoreite = 11.30 barns/electronU=PEWhitmoreite x r Electron Density= 32.52 barns/cc.
Radioactivity:
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Whitmoreite is Not Radioactive
Whitmoreite Classification
Dana Class:
42.11.18.01 (42) Hydrated Phosphates, etc., Containing Hydroxyl or Halogen
(42.11) where (AB)4 (XO4)3 Zq � x(H2O)
(42.11.18) Whitmoreite Group
42.11.18.01 Whitmoreite FeFe2(PO4)2(OH)2•4(H2O) P 21 /c 2/m
42.11.18.02 Arthurite CuFe2(AsO4,PO4,SO4)2(O,OH)2•4(H2O) P 21 /c 2/m
42.11.18.03 Ojuelaite ZnFe2(AsO4)2(OH)2•4(H2O) P 21 /c 2/m
42.11.18.04 Earlshannonite (Mn,Fe)Fe2(PO4)2(OH)2•4(H2O) P 21 /c 2/m
42.11.18.05 Gladiusite ! Fe2(Fe,Mg)4(PO4)(OH)13•H2O P 21 /n 2/m
42.11.18.06 Cobaltarthurite ! CoFe2(AsO4)2(OH)2•4(H2O) P 21 /c 2/m
42.11.18.07 Kunatite CuFe2(PO4)2(OH)2•4H2O P 21 /c 2/m
42.11.18.08 Bendadaite ! FeFe2(AsO4)2(OH)2•4H2O P 21 /c 2/m
Strunz Class:
08.DC.15 08 - PHOSPHATES, ARSENATES, VANADATES
08.D - Phosphates, etc
08.DC -With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1
08.DC.15 Earlshannonite (Mn,Fe)Fe2(PO4)2(OH)2•4(H2O) P 21 /c 2/m
08.DC.15 Arthurite CuFe2(AsO4,PO4,SO4)2(O,OH)2•4(H2O) P 21 /c 2/m
08.DC.15 Ojuelaite ZnFe2(AsO4)2(OH)2•4(H2O) P 21 /c 2/m
08.DC.15 Whitmoreite FeFe2(PO4)2(OH)2•4(H2O) P 21 /c 2/m
08.DC.15 Cobaltarthurite ! CoFe2(AsO4)2(OH)2•4(H2O) P 21 /c 2/m
08.DC.15 Kunatite CuFe2(PO4)2(OH)2•4H2O P 21 /c 2/m
08.DC.15 Bendadaite ! FeFe2(AsO4)2(OH)2•4H2O P 21 /c 2/m
Other Whitmoreite Information
References:
NAME( Dana8) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(Dana8)
See Also:
Links to other databases for Whitmoreite :
1 - Am. Min. Crystal Structure Database
2 - Athena
3 - EUROmin Project
4 - Ecole des Mines de Paris
5 - GeoScienceWorld
6 - Google Images
7 - Google Scholar
8 - Handbook of Mineralogy (MinSocAm)
9 - Handbook of Mineralogy (UofA)
10 - MinDAT
11 - Mineralienatlas (Deutsch)
12 - Online Mineral Museum
13 - QUT Mineral Atlas
14 - Ruff.Info
15 - WWW-MINCRYST
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Whitmoreite
Fe++Fe+++2(PO4)2(OH)2•4(H2O)
Dana No: 42.11.18.01 Strunz No: 08.DC.15
Locality:
Notes:
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