Vivianite Mineral Data
General Vivianite Information
Chemical Formula:
Fe++3(PO4)2•8(H2O)
Composition:
Molecular Weight = 501.61 gm
Iron 33.40 % Fe 42.97 % FeO
Phosphorus 12.35 % P 28.30 % P2 O5
Hydrogen 3.22 % H 28.73 % H2 O
Oxygen 51.03 % O
______ ______
100.00 % 100.00 % = TOTAL OXIDE
Empirical Formula:
Fe2+ 3 (PO4 )2 •8(H2 O)
Environment:
Common secondary mineral in the gossan of metallic ore deposits, pegmatites, sedimentary authigenic mineralization in association with organic materials.
IMA Status:
Valid Species (Pre-IMA) 1817
Locality:
St. Agnes, Cornwall, England Link to MinDat.org Location Data.
Name Origin:
Named after the English mineralogist, J. G. Vivian.
Name Pronunciation:
Vivianite + Pronunciation
Synonym:
Blue Iron Earth
ICSD 200703
PDF 30-662
Vivianite Image
Images:
Images:
Images:
Eosphorite Vivianite
Comments: Bottle-green translucent vivianite crystal (2cm) associated with reddish, micro eosphorite crystals.
Location: Lavra do Énio pegmatite, Galiléia, Governador Valadares, Rio Doce, Minas Gerais, Brazil.
Scale: 3.5 x 3 x 2 cm..
© Tom Loomis / Dakota Matrix
Vivianite Crystallography
Axial Ratios:
a:b:c =0.7501:1:0.3501
Cell Dimensions:
a = 10.06, b = 13.41, c = 4.696, Z = 2; beta = 104.3° V = 613.88 Den(Calc)= 2.71
Crystal System:
Monoclinic - Prismatic H-M Symbol (2/m) Space Group: C 2/m
X Ray Diffraction:
By Intensity(I/Io ): 6.8(1), 2.71(0.67), 2.97(0.67),
Forms:
Mouse
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RMB - Cycle Display Modes
Drag1 - Manipulate Crystal
Drag2 - Resize
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I - Indicies
<space> - Start-Stop Rotation
F - Fit to Screen
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Forms:
( 0 1 0)
( 2 0 1 )
( 2 2 1)
( 1 0 0)
( 1 1 0)
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Physical Properties of Vivianite
Cleavage:
{010} Perfect
Color:
Colorless, Green, Blue, Dark green, Dark bluish green.
Density:
2.6 - 2.7, Average = 2.65
Diaphaneity:
Transparent to translucent to opaque
Fracture:
Sectile - Curved shavings or scrapings produced by a knife blade, (e.g. graphite).
Habit:
Concretionary - Rounded massive fine-grained materials.
Habit:
Divergent - Crystals radiate from a center without producing stellar forms.
Habit:
Earthy - Dull, clay-like texture with no visible crystalline affinities, (e.g. howlite).
Hardness:
1.5-2 - Talc-Gypsum
Luminescence:
Non-fluorescent.
Luster:
Vitreous - Pearly
Streak:
bluish white
Optical Properties of Vivianite
Gladstone-Dale:
CI meas = -0.036 (Excellent) - where the CI = (1-KPDmeas /KC ) CI calc = -0.013 (Superior) - where the CI = (1-KPDcalc /KC )
KPDcalc = 0.2332,KPDmeas = 0.2385,KC = 0.2303 Ncalc = 1.6 - 1.62
Optical Data:
Biaxial (+), a=1.58-1.626, b=1.598-1.662, g=1.627-1.699, bire=0.0470-0.0730, 2V(Calc)=78-88, 2V(Meas)=63.5-83.5. Dispersion none.
Pleochroism (x):
cobalt blue.
Pleochroism (y):
pale greenish yellow.
Calculated Properties of Vivianite
Electron Density:
Bulk Density (Electron Density)=2.72 gm/cc note: Specific Gravity of Vivianite =2.71 gm/cc.
Fermion Index:
Fermion Index = 0.0073307814 Boson Index = 0.9926692186
Photoelectric:
PEVivianite = 10.34 barns/electronU=PEVivianite x r Electron Density= 28.16 barns/cc.
Radioactivity:
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Vivianite is Not Radioactive
Vivianite Classification
Dana Class:
40.03.06.01 (40) Hydrated Phosphates, etc
(40.03) where (A++)3 (XO4)2 � x(H2O)
(40.03.06) Vivianite Group
40.03.06.01 Vivianite Fe3(PO4)2•8(H2O) C 2/m 2/m
40.03.06.02 Baricite (Mg,Fe)3(PO4)2•8(H2O) C 2/m 2/m
40.03.06.03 Erythrite Co3(AsO4)2•8(H2O) I2/m 2/m
40.03.06.04 Annabergite Ni3(AsO4)2•8(H2O) I2/m 2/m
40.03.06.05 Kottigite Zn3(AsO4)2•8(H2O) C 2/m 2/m
40.03.06.06 Parasymplesite Fe3(AsO4)2•8(H2O) C 2/m 2/m
40.03.06.07 Hornesite Mg3(AsO4)2•8(H2O) I2/m 2/m
40.03.06.08 Arupite (Ni,Fe)3(PO4)2•8(H2O) I2/m 2/m
40.03.06.09 Pakhomovskyite ! Co3(PO4)2•8(H2O) C 2/m 2/m
Strunz Class:
08.CE.40 08 - PHOSPHATES, ARSENATES, VANADATES
08.C - Phosphates without Additional Anions, with H2O
08.CE -With only medium-sized cations, RO4:H2O � 1:2.5
08.CE.40 Arupite (Ni,Fe)3(PO4)2•8(H2O) I2/m 2/m
08.CE.40 Annabergite Ni3(AsO4)2•8(H2O) I2/m 2/m
08.CE.40 Baricite (Mg,Fe)3(PO4)2•8(H2O) C 2/m 2/m
08.CE.40 Erythrite Co3(AsO4)2•8(H2O) I2/m 2/m
08.CE.40 Ferrisymplesite Fe3(AsO4)2(OH)3•5(H2O) None
08.CE.40 Hornesite Mg3(AsO4)2•8(H2O) I2/m 2/m
08.CE.40 Kottigite Zn3(AsO4)2•8(H2O) C 2/m 2/m
08.CE.40 Manganohornesite (Mn,Mg)3(AsO4)2•8(H2O) P 21 /c 2/m
08.CE.40 Parasymplesite Fe3(AsO4)2•8(H2O) C 2/m 2/m
08.CE.40 Vivianite Fe3(PO4)2•8(H2O) C 2/m 2/m
08.CE.40 Pakhomovskyite ! Co3(PO4)2•8(H2O) C 2/m 2/m
Other Vivianite Information
See Also:
Links to other databases for Vivianite :
1 - Am. Min. Crystal Structure Database
2 - Amethyst Galleries' Mineral Gallery
3 - Athena
4 - CalTech Mineral Spectroscopy
5 - EUROmin Project
6 - Ecole des Mines de Paris
7 - GeoScienceWorld
8 - Google Images
9 - Google Scholar
10 - Handbook of Mineralogy (MinSocAm)
11 - Handbook of Mineralogy (UofA)
12 - HyperPhysics
13 - MinDAT
14 - Mineralienatlas (Deutsch)
15 - Online Mineral Museum
16 - QUT Mineral Atlas
17 - Ruff.Info
18 - WWW-MINCRYST
19 - YupRocks
20 - theimage
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Vivianite
Fe++3(PO4)2•8(H2O)
Dana No: 40.03.06.01 Strunz No: 08.CE.40
Locality:
Notes:
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