Pitiglianoite Mineral Data
General Pitiglianoite Information
Chemical Formula:
Na6K2Si6Al6O24(SO4)•2(H2O)
Composition:
Molecular Weight = 1,062.62 gm
Potassium 7.36 % K 8.86 % K2 O
Sodium 12.98 % Na 17.50 % Na2 O
Aluminum 15.23 % Al 28.79 % Al2 O3
Silicon 15.86 % Si 33.93 % SiO2
Hydrogen 0.38 % H 3.39 % H2 O
Sulfur 3.02 % S 7.53 % SO3
Oxygen 45.17 % O
______ ______
100.00 % 100.00 % = TOTAL OXIDE
Empirical Formula:
K2 Na6 Si6 Al6 O24 (SO4 )•2(H2 O)
Environment:
In a pumice quarry, in ejected blocks showing metasomatic effects. A product of reaction between trachitic magma and carbonate and sulfate rock in the volcanic vent.
IMA Status:
Approved IMA 1991
Locality:
Casa Collina, Ptigliano, Tuscany, Italy. Link to MinDat.org Location Data.
Name Origin:
Named after the locality.
Name Pronunciation:
Pitiglianoite + Pronunciation
Synonym:
ICSD 66463
IMA1990-012
PDF 46-1390
Pitiglianoite Image
Images:
Pitiglianoite Crystallography
Axial Ratios:
a:c = 1:0.23556
Cell Dimensions:
a = 22.121, c = 5.211, Z = 3; V = 2,208.32 Den(Calc)= 2.40
Crystal System:
Hexagonal - Pyramidal H-M Symbol (6) Space Group: P 63
X Ray Diffraction:
By Intensity(I/Io ): 3.27(1), 4.77(1), 6.39(0.75), 2.36(0.5), 2.77(0.5), 3.69(0.5),
Physical Properties of Pitiglianoite
Cleavage:
{???} Indistinct
Color:
Colorless.
Density:
2.37
Diaphaneity:
Transparent
Fracture:
Brittle - Generally displayed by glasses and most non-metallic minerals.
Habit:
Prismatic - Crystals Shaped like Slender Prisms (e.g. tourmaline).
Hardness:
5 - Apatite
Luster:
Vitreous (Glassy)
Streak:
white
Optical Properties of Pitiglianoite
Gladstone-Dale:
CI meas = -0.04 (Good) - where the CI = (1-KPDmeas /KC ) CI calc = -0.027 (Excellent) - where the CI = (1-KPDcalc /KC )
KPDcalc = 0.2113,KPDmeas = 0.2139,KC = 0.2056 Ncalc = 1.49
Optical Data:
Uniaxial (-), e=1.506, w=1.508, bire=0.0020.
Calculated Properties of Pitiglianoite
Electron Density:
Bulk Density (Electron Density)=2.38 gm/cc note: Specific Gravity of Pitiglianoite =2.40 gm/cc.
Fermion Index:
Fermion Index = 0.0078583631 Boson Index = 0.9921416369
Photoelectric:
PEPitiglianoite = 2.18 barns/electronU=PEPitiglianoite x r electron = 5.18 barns/cc.
Radioactivity:
GRapi = 105.13 (Gamma Ray American Petroleum Institute Units)
Concentration of Pitiglianoite per GRapi unit = 0.95 (%)
Estimated Radioactivity from Pitiglianoite - barely detectable
Pitiglianoite Classification
Dana Class:
76.02.05.11 (76) Tectosilicate Al-Si Framework
(76.02) Feldspathoids and related species
(76.02.05) Cancrinite group
76.02.05.01 Afghanite (Na,Ca,K)8(Si,Al)12O24(SO4,Cl,CO3)3•(H2O) P 63 /mmc, P 63 mc, or P 6 2c Hex
76.02.05.02 Bystrite (Na,K)7Ca(Si6Al6)O24S4.5•(H2O) P 31 c 3m
76.02.05.03 Cancrinite Na6Ca2Al6Si6O24(CO3)2 P 63 6
76.02.05.04 Cancrisilite Na7Al5Si7O24(C03)•3(H2O) P 63 6
76.02.05.05 Davyne Na4K2Ca2Si6Al6O24(SO4)Cl2 P 63 /m 6/m
76.02.05.06 Franzinite [(Na,K)30Ca10][Si30Al30O120](SO4)10•2(H2O) P 32 1 3 2
76.02.05.07 Giuseppettite [Na42K16Ca6]S64Si48Al48O192(SO4)10Cl2•5H2O P 31 c 3m
76.02.05.08 Hydroxycancrinite Na4(AlSiO4)3(OH)•(H2O) P 63 6
76.02.05.09 Liottite (Ca,Na,K)8(Si,Al)12O24[(SO4),(CO3),Cl,OH]4•(H2O) P 6 m2 6 m2
76.02.05.10 Microsommite (Na,Ca,K)7-8(Si,Al)12O24(Cl,SO4)2-3 P 63 22 6 2 2
76.02.05.11 Pitiglianoite Na6K2Si6Al6O24(SO4)•2(H2O) P 63 6
76.02.05.12 Quadridavyne (Na,K)6Ca2Al6Si6O24Cl4 P 63 /m 6/m
76.02.05.13 Sacrofanite (Na,Ca,K)9Si6Al6O24[(OH),(SO4),(CO3),Cl)]4•n(H2O) P 63 /mmc ? 6/m 2/m 2/m
76.02.05.14 Tounkite (Na,Ca,K)8Al6Si6O24(SO4)2Cl•(H2O) P 62 22 6 2 2
76.02.05.15 Vishnevite (Na,Ca,K)6(Si,Al)12O24[(SO4),(CO3),Cl2]2-4•n(H2O) P 63 22 6 2 2
76.02.05.16 Wenkite Ba4Ca6(Si,Al)20O39(OH)2(SO4)3•n(H2O)(?) P 6 2m 6 m2
76.02.05.17 Marinellite ! [(Na,K)42Ca6](Si36Al36O144)(SO4)8Cl2•6(H2O) P 31 c or P 2c Trig
76.02.05.18 Farneseite ! (Na37K9Ca10)S56(Si42Al42)S84O168(SO4)12•6(H2O) P 63 /m 6/m 2/m 2/m
76.02.05.19 Alloriite ! Na5K1.5Ca(Si6Al6O24)(SO4)(OH)0.5•H2O P 31 c 3m
76.02.05.20 Biachellaite (Na,Ca,K)8(Si6Al6O24)(SO4)2(OH)0.5•H2O P 3 3
76.02.05.21 IMA2008-006 ! [Na82.5Ca33K16.5](Si99Al99O396)(SO4)33•4H2O P 3 3
76.02.05.22 Kyanoxalite ! Na7(Al5-6Si6-7O24)(C2O4)0.5-1.0•5H2O P 63 6
76.02.05.23 IMA2008-065 ! (Na,K)6Ca2(Si6Al6O24)Cl2(CO3) P 63 6
Strunz Class:
09.FB.05 09 - SILICATES (Germanates)
09.F - Tektosilicates without Zeolitic H2O
09.FB -Tektosilicates with additional anions
09.FB.05 Bystrite (Na,K)7Ca(Si6Al6)O24S4.5•(H2O) P 31 c 3m
09.FB.05 Afghanite (Na,Ca,K)8(Si,Al)12O24(SO4,Cl,CO3)3•(H2O) P 63 /mmc, P 63 mc, or P 6 2c Hex
09.FB.05 Cancrisilite Na7Al5Si7O24(C03)•3(H2O) P 63 6
09.FB.05 Cancrinite Na6Ca2Al6Si6O24(CO3)2 P 63 6
09.FB.05 Hydroxycancrinite Na4(AlSiO4)3(OH)•(H2O) P 63 6
09.FB.05 Franzinite [(Na,K)30Ca10][Si30Al30O120](SO4)10•2(H2O) P 32 1 3 2
09.FB.05 Liottite (Ca,Na,K)8(Si,Al)12O24[(SO4),(CO3),Cl,OH]4•(H2O) P 6 m2 6 m2
09.FB.05 Davyne Na4K2Ca2Si6Al6O24(SO4)Cl2 P 63 /m 6/m
09.FB.05 Giuseppettite [Na42K16Ca6]S64Si48Al48O192(SO4)10Cl2•5H2O P 31 c 3m
09.FB.05 Quadridavyne (Na,K)6Ca2Al6Si6O24Cl4 P 63 /m 6/m
09.FB.05 Pitiglianoite Na6K2Si6Al6O24(SO4)•2(H2O) P 63 6
09.FB.05 Microsommite (Na,Ca,K)7-8(Si,Al)12O24(Cl,SO4)2-3 P 63 22 6 2 2
09.FB.05 Vishnevite (Na,Ca,K)6(Si,Al)12O24[(SO4),(CO3),Cl2]2-4•n(H2O) P 63 22 6 2 2
09.FB.05 Sacrofanite (Na,Ca,K)9Si6Al6O24[(OH),(SO4),(CO3),Cl)]4•n(H2O) P 63 /mmc ? 6/m 2/m 2/m
09.FB.05 Marinellite ! [(Na,K)42Ca6](Si36Al36O144)(SO4)8Cl2•6(H2O) P 31 c or P 2c Trig
09.FB.05 Tounkite (Na,Ca,K)8Al6Si6O24(SO4)2Cl•(H2O) P 62 22 6 2 2
09.FB.05 IMA2008-065 ! (Na,K)6Ca2(Si6Al6O24)Cl2(CO3) P 63 6
09.FB.05 Farneseite ! (Na37K9Ca10)S56(Si42Al42)S84O168(SO4)12•6(H2O) P 63 /m 6/m 2/m 2/m
09.FB.05 Biachellaite (Na,Ca,K)8(Si6Al6O24)(SO4)2(OH)0.5•H2O P 3 3
09.FB.05 IMA2008-006 ! [Na82.5Ca33K16.5](Si99Al99O396)(SO4)33•4H2O P 3 3
09.FB.05 Alloriite ! Na5K1.5Ca(Si6Al6O24)(SO4)(OH)0.5•H2O P 31 c 3m
Other Pitiglianoite Information
References:
NAME( Dana8) PHYS. PROP.(Dana8) OPTIC PROP.(Dana8)
See Also:
Links to other databases for Pitiglianoite :
1 - Am. Min. Crystal Structure Database
2 - Athena
3 - EUROmin Project
4 - Ecole des Mines de Paris
5 - GeoScienceWorld
6 - Google Images
7 - Google Scholar
8 - Handbook of Mineralogy (MinSocAm)
9 - Handbook of Mineralogy (UofA)
10 - MinDAT
11 - Mineralienatlas (Deutsch)
12 - Online Mineral Museum
13 - QUT Mineral Atlas
14 - Ruff.Info
15 - WWW-MINCRYST
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Pitiglianoite
Na6K2Si6Al6O24(SO4)•2(H2O)
Dana No: 76.02.05.11 Strunz No: 09.FB.05
Locality:
Notes:
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