Phosgenite Mineral Data
General Phosgenite Information
Chemical Formula:
Pb2(CO3)Cl2
Composition:
Molecular Weight = 545.31 gm
Lead 75.99 % Pb 87.73 % PbO2
Carbon 2.20 % C 8.07 % CO2
Chlorine 13.00 % Cl 13.00 % Cl
- %
Cl -2.93 % -O=Cl2
Oxygen 8.80 % O
______ ______
100.00 % 105.87 % = TOTAL OXIDE
Empirical Formula:
Pb2 (CO3 )Cl2
IMA Status:
Valid Species (Pre-IMA) 1841
Locality:
Tsumeb near Otavi, Niambia. Link to MinDat.org Location Data.
Name Origin:
Named from the composition phosgene (COCl2), as the mineral contains this compound.
Name Pronunciation:
Phosgenite + Pronunciation
Synonym:
Cromfordite
Horn Lead
ICSD 4240
PDF 12-218
Phosgenite Image
Images:
Images:
Phosgenite Crystallography
Axial Ratios:
a:c = 1:1.08653
Cell Dimensions:
a = 8.112, c = 8.814, Z = 4; V = 580.00 Den(Calc)= 6.24
Crystal System:
Tetragonal - Ditetragonal Dipyramidal H-M Symbol (4/m 2/m 2/m) Space Group: P 4/mbm
X Ray Diffraction:
By Intensity(I/Io ): 2.79(1), 2.56(0.8), 3.61(0.8),
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Physical Properties of Phosgenite
Cleavage:
{110} Good, {001} Good, {010} Indistinct
Color:
White, Gray, Brownish yellow, Greenish white, Pinkish white.
Density:
6 - 6.3, Average = 6.15
Diaphaneity:
Transparent to translucent
Fracture:
Sectile - Curved shavings or scrapings produced by a knife blade, (e.g. graphite).
Habit:
Massive - Granular - Common texture observed in granite and other igneous rock.
Habit:
Prismatic - Crystals Shaped like Slender Prisms (e.g. tourmaline).
Habit:
Tabular - Form dimensions are thin in one direction.
Hardness:
2.5-3 - Finger Nail-Calcite
Luminescence:
Weakly Fluorescent, Short UV=weak yellow-orange, Long UV=yellow-orange.
Luster:
Adamantine
Streak:
white
Optical Properties of Phosgenite
Dichroism (e):
reddish.
Dichroism (w):
greenish.
Optical Data:
Uniaxial (+), w=2.114, e=2.14, bire=0.0260.
Calculated Properties of Phosgenite
Electron Density:
Bulk Density (Electron Density)=5.22 gm/cc note: Specific Gravity of Phosgenite =6.24 gm/cc.
Fermion Index:
Fermion Index = 0.16 Boson Index = 0.84
Photoelectric:
PEPhosgenite =1,396.07 barns/electronU=PEPhosgenite x r Electron Density=7,284.66 barns/cc.
Radioactivity:
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Phosgenite is Not Radioactive
Phosgenite Classification
Dana Class:
16a.03.04.01 (16a) Carbonates - Hydroxyl or Halogen
(16a.03) where (A B)2 (XO3) Zq
(16a.03.04) Dana Group
16a.03.04.01 Phosgenite Pb2(CO3)Cl2 P 4/mbm 4/m 2/m 2/m
Strunz Class:
05.BE.20 05 - CARBONATES (NITRATES)
05.B - Carbonates with additional anions, without H2O
05.BE -With Pb, Bi
05.BE.20 Phosgenite Pb2(CO3)Cl2 P 4/mbm 4/m 2/m 2/m
Other Phosgenite Information
References:
NAME( Dana8) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(Ford32)
See Also:
Links to other databases for Phosgenite :
1 - Am. Min. Crystal Structure Database
2 - Amethyst Galleries' Mineral Gallery
3 - Athena
4 - EUROmin Project
5 - Ecole des Mines de Paris
6 - GeoScienceWorld
7 - Google Images
8 - Google Scholar
9 - Handbook of Mineralogy (MinSocAm)
10 - Handbook of Mineralogy (UofA)
11 - HyperPhysics
12 - HyperPhysics
13 - MinDAT
14 - Mineral and Gemstone Kingdom
15 - Mineralienatlas (Deutsch)
16 - Online Mineral Museum
17 - QUT Mineral Atlas
18 - Ruff.Info
19 - WWW-MINCRYST
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Phosgenite
Pb2(CO3)Cl2
Dana No: 16a.03.04.01 Strunz No: 05.BE.20
Locality:
Notes:
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