Labuntsovite-Mn Mineral Data
General Labuntsovite-Mn Information
Chemical Formula:
Na4K4(Ba,K)(Mn,Fe)1+x(Ti,Nb)8[Si4O12]4(O,OH)8•n(H2O), n=10-12
Composition:
Molecular Weight = 2,232.12 gm
Potassium 5.96 % K 7.17 % K2 O
Barium 8.00 % Ba 8.93 % BaO
Sodium 2.37 % Na 3.19 % Na2 O
Calcium 0.90 % Ca 1.26 % CaO
Magnesium 0.22 % Mg 0.36 % MgO
Titanium 15.44 % Ti 25.77 % TiO2
Manganese 1.72 % Mn 2.22 % MnO
Niobium 0.83 % Nb 1.19 % Nb2 O5
Aluminum 0.73 % Al 1.37 % Al2 O3
Iron 1.00 % Fe 1.43 % Fe2 O3
Silicon 18.37 % Si 39.30 % SiO2
Hydrogen 0.87 % H 7.79 % H2 O
Oxygen 43.59 % O
______ ______
100.00 % 99.99 % = TOTAL OXIDE
Empirical Formula:
K3.4 Na2.3 Ba1.3 Mn2+ 0.7 Ca0.5 Ti7.2 Fe3+ 0.4 Nb0.2 Mg0.2 Si14.6 Al0.6 O46.32 (OH)9.7 �4.8(H2 O)
Environment:
A hydrothermal alteration product of murmanite in alkalic pegmatites in a differentiated alkalic massif and in carbonatite. Renamed labunsovite in 1955 from titanoelpidite.
IMA Status:
Valid Species (Pre-IMA) 1926 (Dana # Changed from 60.1.3.2)
Locality:
In the Lovozero, Khibiny, and Kovdor massifs and the Vuoriyarvi carbonatite complex, Kola Peninsula, Russia. Link to MinDat.org Location Data.
Name Origin:
Named for Aleksander Nikolaevich Labuntsov and Ekaterina Eutikhieva Labuntsov-Kostyleva, Russian mineralogists.
Name Pronunciation:
Labuntsovite-Mn + Pronunciation
Synonym:
IMA2000-A
Labuntsovite - (60.1.3.2)
Titanoelpidite
Labuntsovite-Mn Image
Images:
Labuntsovite-Mn
Comments: Cinnamon colored crystals of labuntsovite-Mn to 3 mm on dolomite matrix.
Location: Kovdor Mine, Kola Peninsula, Russia.
Scale: Picture size 1.5x2 cm.
© John Veevaert
Labuntsovite-Mn Crystallography
Axial Ratios:
a:b:c =0.956:1:0.885
Cell Dimensions:
a = 14.8, b = 15.48, c = 13.7, Z = 2; beta = 117° V = 2,796.62 Den(Calc)= 2.65
Crystal System:
Monoclinic - Prismatic H-M Symbol (2/m) Space Group: I2/m
X Ray Diffraction:
By Intensity(I/Io ): 3.15(1), 1.543(0.9), 2.56(0.9),
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Physical Properties of Labuntsovite-Mn
Cleavage:
{100} Perfect
Color:
Brownish yellow, Pink, Reddish brown.
Density:
2.89 - 3.02, Average = 2.95
Diaphaneity:
Transparent to Translucent
Fracture:
Brittle - Subconchoidal - Brittle frature with subconchoidal fragments
Habit:
Prismatic - Crystals Shaped like Slender Prisms (e.g. tourmaline).
Hardness:
6 - Orthoclase
Luster:
Greasy (Oily)
Streak:
white
Optical Properties of Labuntsovite-Mn
Gladstone-Dale:
CI meas = 0.047 (Good) - where the CI = (1-KPDmeas /KC ) CI calc = -0.062 (Fair) - where the CI = (1-KPDcalc /KC )
KPDcalc = 0.2755,KPDmeas = 0.247,KC = 0.2593 Ncalc = 1.69 - 1.78
Optical Data:
Biaxial (+), a=1.684-1.695, b=1.693-1.702, g=1.792-1.814, bire=0.1080-0.1190, 2V(Calc)=30-36, 2V(Meas)=20-44.
Pleochroism (x):
yellowish.
Pleochroism (z):
yellowish brown.
Calculated Properties of Labuntsovite-Mn
Electron Density:
Bulk Density (Electron Density)=2.88 gm/cc note: Specific Gravity of Labuntsovite-Mn =2.96 gm/cc.
Fermion Index:
Fermion Index = 0.04 Boson Index = 0.96
Photoelectric:
PELabuntsovite-Mn = 38.89 barns/electronU=PELabuntsovite-Mn x r electron = 112.00 barns/cc.
Radioactivity:
GRapi = 83.77 (Gamma Ray American Petroleum Institute Units)
Concentration of Labuntsovite-Mn per GRapi unit = 1.19 (%)
Estimated Radioactivity from Labuntsovite-Mn - barely detectable
Labuntsovite-Mn Classification
Dana Class:
60.01.03e.01 (60) Cyclosilicate Four-Membered Rings
(60.01) as Titanosilicates
(60.01.03e) Labuntsovite Group (Labuntsovite subgroup Monoclinic [C2/m])
60.01.03e.01 Labuntsovite-Mn ! Na4K4(Ba,K)(Mn,Fe)1x(Ti,Nb)8[Si4O12]4(O,OH)8•n(H2O),n=10-12 I2/m 2/m
60.01.03e.02 Labuntsovite-Mg ! Na4K4(Ba,K)(Mg,Fe)1xTi8(Si4O12)4(O,OH)8•10(H2O) C 2/m 2/m
60.01.03e.03 Labuntsovite-Fe ! Na4K4(Ba,K)2(Fe,Mg,Mn)1xTi8(Si4O12)4(O,OH)8•10(H2O) C 2/m 2/m
60.01.03e.04 Paratsepinite-Na ! (Na,Sr,K,Ca)7(Ti,Nb)8[Si4O12]4(O,OH)8•n(H2O)n~8 C 2/m 2/m
60.01.03e.05 Gjerdingenite-Mn ! (K,Na)2(Mn,Fe)(Nb,Ti)4(Si4O12)2(O,OH)4•6(H2O) C 2/m 2/m
60.01.03e.06 Gjerdingenite-Fe ! K2[(H2O)2(Fe,Mn)][(Nb,Ti)4(Si4O12)2(O,OH)4]•4(H2O) C 2/m 2/m
60.01.03e.07 Gjerdingenite-Ca ! K2Ca(Nb,Ti)4(Si4O12)2(O,OH)4•6H2O C 2/m 2/m
60.01.03e.08 Gjerdingenite-Na ! (K,Na)2Na(Nb,Ti)4(Si4O12)2(OH,O)4•5H2O C 2/m 2/m
Strunz Class:
09.CE.30e 09 - SILICATES (Germanates)
09.C - Cyclosilicates
09.CE -[Si4O12]8- 4-membered single rings (vierer-Einfachringe),
09.CE.30e Labuntsovite-Mn Na4K4(Ba,K)(Mn,Fe)1x(Ti,Nb)8[Si4O12]4(O,OH)8•n(H2O),n=10-12 I2/m 2/m
09.CE.30e Labuntsovite-Mg ! Na4K4(Ba,K)(Mg,Fe)1xTi8(Si4O12)4(O,OH)8•10(H2O) C 2/m 2/m
09.CE.30e Labuntsovite-Fe ! Na4K4(Ba,K)2(Fe,Mg,Mn)1xTi8(Si4O12)4(O,OH)8•10(H2O) C 2/m 2/m
Other Labuntsovite-Mn Information
References:
NAME( AntBidBlaNic2) PHYS. PROP.(AntBidBlaNic2) OPTIC PROP.(AntBidBlaNic2)
See Also:
Links to other databases for Labuntsovite-Mn :
1 - Am. Min. Crystal Structure Database
2 - Athena
3 - GeoScienceWorld
4 - Google Images
5 - Google Scholar
6 - MinDAT
7 - Mineralienatlas (Deutsch)
8 - Online Mineral Museum
9 - QUT Mineral Atlas
10 - Ruff.Info
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Labuntsovite-Mn
Na4K4(Ba,K)(Mn,Fe)1+x(Ti,Nb)8[Si4O12]4(O,OH)8•n(H2O), n=10-12
Dana No: 60.01.03e.01 Strunz No: 09.CE.30e
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