Gutkovaite-Mn Mineral Data
General Gutkovaite-Mn Information
Chemical Formula:
CaK2Mn(Ti,Nb)4(Si4O12)2(O,OH)4•5(H2O)
Composition:
Molecular Weight = 1,243.09 gm
Potassium 5.19 % K 6.25 % K2 O
Barium 0.88 % Ba 0.99 % BaO
Sodium 0.13 % Na 0.17 % Na2 O
Strontium 7.47 % Sr 8.84 % SrO
Calcium 3.22 % Ca 4.51 % CaO
Magnesium 0.10 % Mg 0.16 % MgO
Zirconium 0.07 % Zr 0.10 % ZrO2
Titanium 13.83 % Ti 23.07 % TiO2
Manganese 3.62 % Mn 4.68 % MnO
Niobium 3.36 % Nb 4.81 % Nb2 O5
Aluminum 0.09 % Al 0.16 % Al2 O3
Zinc 0.11 % Zn 0.13 % ZnO
Iron 0.45 % Fe 0.58 % FeO
Silicon 18.07 % Si 38.67 % SiO2
Hydrogen 0.91 % H 8.17 % H2 O
Oxygen 42.49 % O
______ ______
100.00 % 101.29 % = TOTAL OXIDE
Empirical Formula:
CaNa0.07 K1.65 Ba0.08 Sr1.06 Mn2+ 0.82 Fe2+ 0.1 Mg0.05 Zn0.02 Ti3.59 Nb0.45 Zr0.01 Si8 Al0.04 O24.14
O2.47 (OH)1.53 �4.87(H2 O)
Environment:
Pegmitite within nepheline syenite. (labuntosovite group; structure)
IMA Status:
Approved IMA 2002 (Dana # Added)
Locality:
Mooount Maly Mannepakhk, Khibiny alkaline massif, Kola Peninsula, Russia. Link to MinDat.org Location Data.
Name Origin:
Named for N. N. Gukova (1896-1960?), Russian mineralogist..
Synonym:
IMA2001-038
Gutkovaite-Mn Image
Images:
Gutkovaite-Mn
Comments: Pale pink gutkovaite-(Mn) in matrix.
Location: Malyi Mannepakhk Mt., Chibiny, Kola, Russia.
Scale: Specimen Size 1.5x2 cm.
© Diederik Visser
Gutkovaite-Mn Crystallography
Axial Ratios:
a:b:c =1.0295:1:0.5587
Cell Dimensions:
a = 14.3, b = 13.889, c = 7.76, Z = 2; beta = 117.51° V = 1,366.97 Den(Calc)= 3.02
Crystal System:
Monoclinic - Domatic H-M Symbol (m) Space Group: Cm
X Ray Diffraction:
By Intensity(I/Io ): 3.05(1)(241 ,240), 3.22(0.9)(421 ,402 ,400), 7(0.7)(020,001),
2.48(0.6)(441 ,403,401), 2.57(0.5)(242 ,241), 6.33(0.5)(201 ,200), 1.428(0.3), 1
Physical Properties of Gutkovaite-Mn
Cleavage:
None
Color:
Pale yellowish pink.
Density:
2.83
Diaphaneity:
Transparent to Translucent
Fracture:
Brittle - Uneven - Very brittle fracture producing uneven fragments.
Habit:
Prismatic - Crystals Shaped like Slender Prisms (e.g. tourmaline).
Hardness:
5 - Apatite
Luster:
Vitreous (Glassy)
Streak:
white
Optical Properties of Gutkovaite-Mn
Gladstone-Dale:
CI meas = 0.004 (Superior) - where the CI = (1-KPDmeas /KC ) CI calc = 0.066 (Fair) - where the CI = (1-KPDcalc /KC )
KPDcalc = 0.2421,KPDmeas = 0.2583,KC = 0.2593 Ncalc = 1.73 - 1.78
Optical Data:
Biaxial (+), a=1.688, b=1.7, g=1.805, bire=0.1170, 2V(Calc)=40, 2V(Meas)=35. Dispersion dispersion not observed.
Calculated Properties of Gutkovaite-Mn
Electron Density:
Bulk Density (Electron Density)=2.76 gm/cc note: Specific Gravity of Gutkovaite-Mn =2.83 gm/cc.
Fermion Index:
Fermion Index = 0.03 Boson Index = 0.97
Photoelectric:
PEGutkovaite-Mn = 21.70 barns/electronU=PEGutkovaite-Mn x r electron = 59.97 barns/cc.
Radioactivity:
GRapi = 73.09 (Gamma Ray American Petroleum Institute Units)
Concentration of Gutkovaite-Mn per GRapi unit = 1.37 (%)
Estimated Radioactivity from Gutkovaite-Mn - barely detectable
Gutkovaite-Mn Classification
Dana Class:
60.01.03f.01 (60) Cyclosilicate Four-Membered Rings
(60.01) as Titanosilicates
(60.01.03f) Labuntsovite Group (Gutkovaite subgroup Monoclinic [Cm])
60.01.03f.01 Gutkovaite-Mn ! CaK2Mn(Ti,Nb)4(Si4O12)2(O,OH)4•5(H2O) Cm m
60.01.03f.02 Alsakharovite-Zn ! NaSrKZn(Ti,Nb)4(Si4O12)2(O,OH)4•7(H2O) Cm m
60.01.03f.03 Neskevaaraite-Fe ! NaK3Fe(Ti,Nb)4(Si4O12)2(O,OH)4•6(H2O) Cm m
Strunz Class:
09.CE.30h 09 - SILICATES (Germanates)
09.C - Cyclosilicates
09.CE -[Si4O12]8- 4-membered single rings (vierer-Einfachringe),
09.CE.30h Gutkovaite-Mn ! CaK2Mn(Ti,Nb)4(Si4O12)2(O,OH)4•5(H2O) Cm m
09.CE.30h Alsakharovite-Zn ! NaSrKZn(Ti,Nb)4(Si4O12)2(O,OH)4•7(H2O) Cm m
09.CE.30h Neskevaaraite-Fe ! NaK3Fe(Ti,Nb)4(Si4O12)2(O,OH)4•6(H2O) Cm m
Other Gutkovaite-Mn Information
References:
NAME( AmMin, v 88, p 931) PHYS. PROP.(AmMin, v 88, p 931) OPTIC PROP.(AmMin, v 88, p 931)
See Also:
Links to other databases for Gutkovaite-Mn :
1 - Am. Min. Crystal Structure Database
2 - Athena
3 - GeoScienceWorld
4 - Google Images
5 - Google Scholar
6 - MinDAT
7 - Mineralienatlas (Deutsch)
8 - Online Mineral Museum
9 - QUT Mineral Atlas
10 - Ruff.Info
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Gutkovaite-Mn
CaK2Mn(Ti,Nb)4(Si4O12)2(O,OH)4•5(H2O)
Dana No: 60.01.03f.01 Strunz No: 09.CE.30h
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