Ercitite Mineral Data
General Ercitite Information
Chemical Formula:
Na2(H2O)4[Mn+++2(OH)2(PO4)2]
Composition:
Molecular Weight = 225.83 gm
Sodium 9.06 % Na 12.21 % Na2 O
Calcium 0.71 % Ca 0.99 % CaO
Manganese 12.89 % Mn 18.53 % Mn2 O3
Iron 11.38 % Fe 16.26 % Fe2 O3
Phosphorus 13.85 % P 31.74 % P2 O5
Hydrogen 2.23 % H 19.94 % H2 O
Oxygen 49.88 % O
______ ______
100.00 % 99.68 % = TOTAL OXIDE
Empirical Formula:
Na0.89 Ca0.04 Mn3+ 0.53 Fe3+ 0.46 (PO4 )1.01 (OH)•2(H2 O)
Environment:
Strongly oxidizing, low-temperature hydrothermal alteration. Found as an overgrowth on collinsite, fairfieldite, whitlockite, and other phosphates on a fracture surface the cuts an altered nodule of lithophllite.
IMA Status:
Approved IMA 1999 (Dana # Added)
Locality:
Tanco pegmatite at Bernic Lake, southeastern Maitoba, Canada. Link to MinDat.org Location Data.
Name Origin:
Named for mineralogist T. Scott Ercit (1957-) of the Canadian Museum of Nature, Ottawa, Canada.
Synonym:
IMA1999-036
Ercitite Image
Images:
Ercitite
Comments: Back-scattered electron images of ercitite (medium gray) showing lath-shaped habit and cleavages and splintering on mechanical disturbance. W: whitlockite, F: fairfieldite, C: unidentified. (CanMin, v 38, p 896).
Location: Tanco pegmatite, southeastern Manitoba, Canada.
Scale: Image size 150 µ-m.
© Canadian Mineralogist
Ercitite Crystallography
Axial Ratios:
a:b:c =0.7144:1:2.2811
Cell Dimensions:
a = 6.2499, b = 8.7479, c = 19.9554, Z = 8; V = 1,091.03 Den(Calc)= 2.75
Crystal System:
Orthorhombic - Dipyramidal H-M Symbol (2/m 2/m 2/m) Space Group: C mca
X Ray Diffraction:
By Intensity(I/Io ): 9.9(1)(020), 2.664(0.8)(141), 3.126(0.6)(150,051), 3.273(0.6)(141), 4.92(0.5)(011,110), 2.376(0.4)(171 ), 2.542(0.4)(200,002), 4.102(0.3),
Physical Properties of Ercitite
Cleavage:
{101} Very Good, {010} Very Good
Color:
Dark brown, Black.
Diaphaneity:
Translucent
Fracture:
Brittle - Irregular - Very brittle fracture producing irregular fragments
Habit:
Lath - Shaped like a small, thin plaster lath, tabular (rectangular) in shape.
Habit:
Microscopic Crystals - Crystals visible only with microscopes.
Hardness:
3-4 - Calcite-Fluorite
Luster:
Vitreous (Glassy)
Streak:
beige
Optical Properties of Ercitite
Gladstone-Dale:
CI calc = -0.01 (Superior) - where the CI = (1-KPDcalc /KC ) KPDcalc = 0.2607,KC = 0.2582 Ncalc = 1.71
Optical Data:
Biaxial (+), a=1.699, b=1.715, g=1.737, bire=0.0380
Calculated Properties of Ercitite
Electron Density:
Bulk Density (Electron Density)=2.73 gm/cc note: Specific Gravity of Ercitite =2.75 gm/cc.
Fermion Index:
Fermion Index = 0.0026639768 Boson Index = 0.9973360232
Photoelectric:
PEErcitite = 7.50 barns/electronU=PEErcitite x r Electron Density= 20.50 barns/cc.
Radioactivity:
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Ercitite is Not Radioactive
Ercitite Classification
Dana Class:
42.11.17.02 (42) Hydrated Phosphates, etc., Containing Hydroxyl or Halogen
(42.11) where (AB)4 (XO4)3 Zq � x(H2O)
(42.11.17) Bermanite Group
42.11.17.01 Bermanite MnMn2(PO4)2(OH)2•4(H2O) P 21 2
42.11.17.02 Ercitite ! Na2(H2O)4[Mn2(OH)2(PO4)2] C mca 2/m 2/m 2/m
Strunz Class:
08.DJ.35 08 - PHOSPHATES, ARSENATES, VANADATES
08.D - Phosphates, etc
08.DJ -With large and medium-sized cations, (OH, etc.):RO4 = 1:l
08.DJ.35 Ercitite ! Na2(H2O)4[Mn2(OH)2(PO4)2] C mca 2/m 2/m 2/m
Other Ercitite Information
References:
NAME( AmMin, vol 86, p767) PHYS. PROP.(AmMin, v86:767; CanMin, v47:173) OPTIC PROP.(AmMin, vol 86, p767)
See Also:
Links to other databases for Ercitite :
1 - Am. Min. Crystal Structure Database
2 - Athena
3 - GeoScienceWorld
4 - Google Images
5 - Google Scholar
6 - MinDAT
7 - Mineralienatlas (Deutsch)
8 - Online Mineral Museum
9 - QUT Mineral Atlas
10 - Ruff.Info
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Ercitite
Na2(H2O)4[Mn+++2(OH)2(PO4)2]
Dana No: 42.11.17.02 Strunz No: 08.DJ.35
Locality:
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