Brownmillerite Mineral Data
General Brownmillerite Information
Chemical Formula:
Ca2(Al,Fe+++)2O5
Composition:
Molecular Weight = 240.09 gm
Calcium 33.39 % Ca 46.71 % CaO
Aluminum 12.36 % Al 23.36 % Al2 O3
Iron 20.93 % Fe 26.93 % FeO
Oxygen 33.32 % O
______ ______
100.00 % 97.00 % = TOTAL OXIDE
Empirical Formula:
Ca2 Al1.1 Fe2+ 0.9 O5
Environment:
Thermally metamorphosed limestone blocks included in volcanic rocks.
IMA Status:
Approved IMA 1964
Locality:
Ettringer-Bellerberg volcano, near Mayen, Eifel district, Germay. Link to MinDat.org Location Data.
Name Origin:
Named for Lorrin Thomas Brownmiller (1902-), Chef chemist of the Alpha Portland Cement Company, Easton, Pennsylvania, USA.
Name Pronunciation:
Brownmillerite + Pronunciation
Synonym:
ICSD 9197
PDF 30-226
Brownmillerite Image
Images:
Images:
Brownmillerite Crystallography
Axial Ratios:
a:b:c =0.3822:1:0.3698
Cell Dimensions:
a = 5.52, b = 14.44, c = 5.34, Z = 4; V = 425.64 Den(Calc)= 3.75
Crystal System:
Orthorhombic - Dipyramidal H-M Symbol (2/m 2/m 2/m) Space Group: Ibmm
X Ray Diffraction:
By Intensity(I/Io ): 2.65(1), 2.78(0.5), 7.19(0.5),
Physical Properties of Brownmillerite
Color:
Reddish brown.
Density:
3.76
Diaphaneity:
Semitransparent
Habit:
Platy - Sheet forms (e.g. micas).
Habit:
Square - Occurs as square crystals in shape or outline.
Streak:
light brown
Optical Properties of Brownmillerite
Gladstone-Dale:
CI meas = -0.354 (Poor) - where the CI = (1-KPDmeas /KC ) CI calc = -0.358 (Poor) - where the CI = (1-KPDcalc /KC )
KPDcalc = 0.2676,KPDmeas = 0.2668,KC = 0.1971 Ncalc = 1.74
Optical Data:
Biaxial (-), a=1.96, b=2.01, g=2.04, bire=0.0800, 2V(Calc)=72, 2V(Meas)=75.
Pleochroism (x):
yellow brown.
Pleochroism (y):
yellow brown.
Pleochroism (z):
dark brown.
Calculated Properties of Brownmillerite
Electron Density:
Bulk Density (Electron Density)=3.69 gm/cc note: Specific Gravity of Brownmillerite =3.76 gm/cc.
Fermion Index:
Fermion Index = 0.0050487097 Boson Index = 0.9949512903
Photoelectric:
PEBrownmillerite = 10.73 barns/electronU=PEBrownmillerite x r Electron Density= 39.57 barns/cc.
Radioactivity:
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Brownmillerite is Not Radioactive
Brownmillerite Classification
Dana Class:
07.11.02.01 (07) Multiple Oxides
(07.11) as titano-oxides with [4] and [6] substitutions
(07.11.02) Dana Group
07.11.02.01 Brownmillerite Ca2(Al,Fe)2O5 Ibmm 2/m 2/m 2/m
07.11.02.02 Srebrodolskite Ca2Fe2O5 P nma 2/m 2/m 2/m
Strunz Class:
04.AC.10 04 - OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodate
04.A - Metal:Oxygen = 2.1 and 1:1
04.AC -M:O = 1:1 (and up to 1:1.25); with large cations (� smaller ones)
04.AC.10 Brownmillerite Ca2(Al,Fe)2O5 Ibmm 2/m 2/m 2/m
04.AC.10 Srebrodolskite Ca2Fe2O5 P nma 2/m 2/m 2/m
Other Brownmillerite Information
References:
NAME( AntBidBlaNic2) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(Enc. of Minerals,2nd ed.,1990)
See Also:
Links to other databases for Brownmillerite :
1 - Am. Min. Crystal Structure Database
2 - Athena
3 - EUROmin Project
4 - Ecole des Mines de Paris
5 - GeoScienceWorld
6 - Google Images
7 - Google Scholar
8 - Handbook of Mineralogy (MinSocAm)
9 - Handbook of Mineralogy (UofA)
10 - MinDAT
11 - Mineralienatlas (Deutsch)
12 - Online Mineral Museum
13 - QUT Mineral Atlas
14 - Ruff.Info
15 - WWW-MINCRYST
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Brownmillerite
Ca2(Al,Fe+++)2O5
Dana No: 07.11.02.01 Strunz No: 04.AC.10
Locality:
Notes:
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